I have in my head that this character is female, a former US Marshal, but eventually came to lead a team known as FETCH, Find Enhanced Targets, Capture And Hold, trained professionals who go after individuals who abuse their powers, and sometimes the highest bidder.
I was curious as to ideas about what led to her departing the Marshals, and what skills or abilities she may have?
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Well maybe just spout off a few ideas that popped into my own head. Maybe this 'Mancatcher' probably has a superiority complex or slowly began to develop one during her time with FETCH. This could've likely happened over maybe one too many successful missions that she likely had led. In turn, this caused for the character to find FETCH a waste of their own time and resources if their own tactical knowledge and intellect is what made them (as Wolverine would say) "The best she is at what she does" thus causing her to depart from the team.
As for skills and abilities, I would probably say some of the aforementioned tactical know-how could work given their past relationship with this ex-team. Likely is proficient in one or more martial arts just a precaution for if they are to be found in some place alone without any sort of weapons or equipment tasked with getting them out of tight situations? This all coming from the top of my head so feel free to poke some holes in things you don't see fit.
"If I am to die in battle, Remember me for who I was and not what I've become..."